Bonfire Trouble Across The North West
6 November 2018, 14:56 | Updated: 6 November 2018, 15:10
Pictures on social media appear to show his burnt clothing and red marks on his skin it happened at around 8.20pm on Lime Street in Liverpool city centre.
It comes as several emergency services across the country said staff had come under attack on Guy Fawkes Night while going about their duties.
Andy Shute, who volunteers for the Paper Cup homeless project in Liverpool, said the victim was a former Army serviceman who said he was targeted by four teenagers.
He says "In the worst case we could be looking at a guy having his leg amputated today.
"As they walked past him one of them said 'have a sparking good night mate', and after that he could smell burning and see his jacket was alight.
"He said he had dealt with flash bangs in the army and his leg would've been a lot worse were his wallet not in the way.
"It's appalling what people are prepared to do to get their kicks."
Merseyside Police said they had not located the homeless man so far, but inquiries are ongoing.
Chief Inspector Paddy Kelly said: "This appears to be a shocking incident and currently our main priority is to locate the victim and ensure he is safe and well.
"We are carrying out thorough witness and CCTV inquiries in Lime Street and the surrounding areas and I would urge anyone with information to please come forward.
"To misuse fireworks is highly irresponsible behaviour which will not be tolerated, and we are determined to locate the offenders and put them before the courts."
A short distance away, fire crews escaped unharmed after a man shot a missile in their direction, Merseyside Fire and Rescue service said.
Elsewhere, Preston police said an egg and fireworks were launched at a squad car on New Hall Lane.
On Saturday, a Moscow watchdog called Winston with a heart condition died after "flying into a panic" from a nearby fireworks display, the Dogs 4 Rescue home in Manchester said.
An online petition calling for a ban on the sale of fireworks to the public has reached more than 163,000 signatures.
It states: "They scare animals, young children and people with a phobia.
"They injure thousands of people every year. They cause damage to buildings, vehicles, emergency vehicles etc. Lastly Kids are STILL being sold them."