Jennifer Aniston, Brad Pitt and Angelina Jolie.
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All Is Fair In Love And War! Celebrity Love Triangles
2. Jennifer Aniston, Brad Pitt and Angelina Jolie.
Brad and Angelina set tongues wagging due to their chemistry on the set of 'Mr and Mrs Smith' leaving some wondering if they struck up a romance while Brad was still married to Jennifer Aniston. Brad had been in a seven year relationship with the the former 'Friends' star when he met Angelina on set in 2004, and whilst he insists they never had an affair the couple became official shortly after his marriage to Jen fell apart in January 2005.